Title of article
Palladium-catalyzed regio- and diastereo-selective allylic alkylation using 2-(diphenylphosphino)benzoic acid: construction of vicinal quaternary and tertiary carbon centers
Author/Authors
Motoi Kawatsura، نويسنده , , Daiji Ikeda، نويسنده , , Yuji Komatsu، نويسنده , , Kana Mitani، نويسنده , , Takeshi Tanaka، نويسنده , , Junichi Uenishi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2007
Pages
10
From page
8815
To page
8824
Abstract
The palladium-catalyzed regio- and diastereo-selective allylic alkylation of allyl acetates with carbon nucleophiles occurred. The stereochemistry was highly controlled by the palladium catalyst with 2-(diphenylphosphino)benzoic acid as the ligand, and vicinal quaternary and tertiary carbon centers were constructed.
Keywords
Palladium , Catalyst , Regioselectivity , Quaternary carbon center , Diastereoselectivity
Journal title
Tetrahedron
Serial Year
2007
Journal title
Tetrahedron
Record number
1091602
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