• Title of article

    Allene–alkyne cross-coupling for stereoselective synthesis of substituted 1,4-dienes and cross-conjugated trienes

  • Author/Authors

    Heidi L. Shimp، نويسنده , , Alissa Hare، نويسنده , , Martin McLaughlin، نويسنده , , Glenn C. Micalizio، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2008
  • Pages
    9
  • From page
    3437
  • To page
    3445
  • Abstract
    Titanium-mediated cross-coupling of allenic alcohols with alkynes has been investigated. Divergent reaction pathways were discovered that provide either stereodefined 1,4-dienes or substituted cross-conjugated trienes. In short, allene substitution plays a critical role in the determination of reaction pathway.
  • Journal title
    Tetrahedron
  • Serial Year
    2008
  • Journal title
    Tetrahedron
  • Record number

    1093945