Title of article
Catalytic cycloisomerisation of 1,6-dienes in ionic liquids
Author/Authors
Xiaowei Miao، نويسنده , , Joanna Feder-Kubis، نويسنده , , Cédric Fischmeister، نويسنده , , Juliusz Pernak، نويسنده , , Pierre H. Dixneuf، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2008
Pages
4
From page
3687
To page
3690
Abstract
The ruthenium and palladium catalysed cycloisomerisation of 1,6-dienes in [bdmim][PF6], a room temperature ionic liquid (RTIL), is presented. The catalytic system comprising of [RuCl2(COD)]n in the presence of iPrOH was found to be particularly efficient and selective for the cycloisomerisation of the N,N-diallyltosylamide. This system can be reused several times without loss of performances and displays catalytic activity after a long storage period in the IL.
Keywords
Cycloisomerisation , 6-Dienes , Ionic liquids , Recycling , Palladium , 1 , Ruthenium
Journal title
Tetrahedron
Serial Year
2008
Journal title
Tetrahedron
Record number
1093972
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