• Title of article

    Cycloisomerization of (arene)chromium complexes with enyne by gold(I) catalyst for axially chiral biaryls

  • Author/Authors

    Christophe Michon، نويسنده , , Suyun Liu، نويسنده , , Shinya Hiragushi، نويسنده , , Junichi Uenishi، نويسنده , , Motokazu Uemura، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2008
  • Pages
    7
  • From page
    11756
  • To page
    11762
  • Abstract
    Planar chiral arene chromium complexes with enyne bond gave stereoselectively axial biaryl chromium complexes by gold(I) catalyzed cycloisomerization in good yields. Arene chromium complexes with enyne bonds were treated with triphenylphosphine gold bis(trifluoromethanesulfonyl)imidate in methylene chloride to give anti-biaryl monochromium complexes without formation of stereoisomers.
  • Journal title
    Tetrahedron
  • Serial Year
    2008
  • Journal title
    Tetrahedron
  • Record number

    1094910