Title of article
Gold-catalyzed cycloisomerizations of ene-ynamides
Author/Authors
Sylvain Couty، نويسنده , , Christophe Meyer، نويسنده , , Janine Cossy، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
24
From page
1809
To page
1832
Abstract
The gold-catalyzed cycloisomerizations of 1,6-ene-ynamides proceed under mild conditions and lead to cyclobutanones from terminal or trimethylsilyl substituted ynamides, or to carbonyl compounds bearing a 2,3-methanopyrrolidine subunit from substrates possessing a propargylic alcohol moiety. High diastereoselectivities are observed with 1,6-ene-ynamides having a stereocenter at the α or β position of the nitrogen atom.
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1095152
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