Title of article
Percycloalkylated cyclohexanes: attempted synthesis of a trispropellane
Author/Authors
Karl Justus، نويسنده , , Tobias Beck، نويسنده , , Mathias Noltemeyer، نويسنده , , Lutz Fitjer، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
7
From page
5192
To page
5198
Abstract
The acid catalyzed rearrangement of two cyclohexanols of spiroannelated four-membered rings has been studied. In accordance with molecular mechanics calculations, far-reaching reorganizations with formation of unsaturated hexacyclic systems, including a fully cycloalkylated cyclohexene with a bispropellane partial structure, were observed. Attempts to convert this bispropellane to a trispropellane failed.
Keywords
Molecular mechanics , Polyspiranes , polycyclic systems , rearrangements
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1097145
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