Title of article
The sulfinyl moiety in Lewis base-promoted allylations
Author/Authors
J. Robin Fulton، نويسنده , , Lamin M. Kamara، نويسنده , , Simon C. Morton، نويسنده , , Gareth J. Rowlands، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
8
From page
9134
To page
9141
Abstract
By employing Senanayakeʹs oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared and provided the first examples of sulfinamides promoting the allylation of benzaldehyde and N-benzoylhydrazones with allyltrichlorosilane. The optimum sulfinamide-derived Lewis base promoter displays comparable activity to the best sulfinyl-based Lewis bases reported. The use of bis-sulfoxides is also discussed.
Keywords
Asymmetric catalysis , Allylation , sulfinamides , sulfoxides , Lewis base
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1099183
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