Title of article
Organocatalyzed Tsuji–Trost reaction: a new method for the closure of five- and six-membered rings
Author/Authors
Bojan Vulovic، نويسنده , , Filip Bihelovic، نويسنده , , Radomir Matovic، نويسنده , , Radomir N. Saicic، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2009
Pages
10
From page
10485
To page
10494
Abstract
A combination of organotransition metal catalysis and organocatalysis allows for Tsuji–Trost 5-exo- and 6-exo-cyclizations of aldehydes. This transformation can also be accomplished as a catalytic asymmetric reaction, which affords vinylcyclopentane derivatives with up to 98%ee.
Keywords
enantioselective catalysis , cyclopentanes , cyclohexanes , Organocatalysis , ?-Allylpalladium complexes , Cyclization
Journal title
Tetrahedron
Serial Year
2009
Journal title
Tetrahedron
Record number
1100343
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