Title of article
Facile oxidative hydrolysis of acetals to esters using hypervalent iodine(III)/LiBr combination in water
Author/Authors
Waraporn Panchan، نويسنده , , Supanimit Chiampanichayakul، نويسنده , , Deanna L. Snyder، نويسنده , , Siriporn Yodbuntung، نويسنده , , Manat Pohmakotr، نويسنده , , Vichai Reutrakul، نويسنده , , Thaworn Jaipetch، نويسنده , , Chutima Kuhakarn، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
4
From page
2732
To page
2735
Abstract
The combination of (diacetoxy)iodobenzene (PhI(OAc)2, DIB) and lithium bromide (LiBr) efficiently oxidized cyclic and acyclic acetals to the corresponding hydroxyalkyl carboxylic esters and simple esters in good to excellent yields. The merits of this reaction are that it employs commercially available and non-explosive hypervalent iodine(III) reagent, water as the solvent, a short reaction time, and mild reaction conditions.
Keywords
Acetal , Hydroxyalkyl carboxylic esters , (Diacetoxy)iodobenzene , DIB , Oxidative hydrolysis
Journal title
Tetrahedron
Serial Year
2010
Journal title
Tetrahedron
Record number
1100720
Link To Document