Title of article
One-pot synthesis of chiral bicyclo[3.3.0]octatrienes using diphenylprolinol silyl ether-mediated ene-type reaction
Author/Authors
Hiroaki Gotoh، نويسنده , , Hiroshi Ogino، نويسنده , , Hayato Ishikawa، نويسنده , , Yujiro Hayashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2010
Pages
6
From page
4894
To page
4899
Abstract
Chiral bicyclo[3.3.0]octatrienes with excellent enantioselectivity were synthesized from the simple starting materials of α,β-unsaturated aldehyde and cyclopentadiene via one-pot operation, which consisted of a diphenylprolinol silyl ether-mediated ene-type reaction, intramolecular addition reaction of cyclopentadiene moiety with aldehyde and dehydration reaction.
Keywords
Organocatalyst , asymmetric reaction , Ene-reaction , One-pot reaction
Journal title
Tetrahedron
Serial Year
2010
Journal title
Tetrahedron
Record number
1100977
Link To Document