Title of article
Domino Diels–Alder reactions of N-methoxyethyl-7-oxa-norbornadiene-2,3-dicarboximide: an elusive, highly reactive dienophile
Author/Authors
Davor Margetic، نويسنده , , Douglas N. Butler، نويسنده , , Ronald N. Warrener، نويسنده , , Yasujiro Murata، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
9
From page
1580
To page
1588
Abstract
Flash vacuum pyrolysis (FVP) has been used to generate the novel 7-oxa-norbornadiene-2,3-dicarboxylic imide that in situ gave an unprecedented cycloaddition reaction cascade with the imidofuran, a side-product of FVP. Stereoselectivity of cycloadditions was studied with the aid of density functional calculations, which fully support observed exo/endo-selectivity.
Keywords
Furan , flash vacuum pyrolysis , Transition states , Diels–Alder reaction , DFT calculations
Journal title
Tetrahedron
Serial Year
2011
Journal title
Tetrahedron
Record number
1102983
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