Title of article
Functionalized 2-Chlorocyclopropanecarboxylates through the MIRC Reaction
Author/Authors
Kimpe، Norbert De نويسنده , , Giubellina، Nicola نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-975
From page
976
To page
0
Abstract
Addition of 3,3-dichloro-1-azaallylic anions to acrylates smoothly gave cis2-chloro-2-imidoylcyclopropanecarboxylates with complete diastereoselection. The resulting cyclopropanes are reduced to 2(aminomethyl)-2-chlorocyclopropanecarboxylates or hydrolyzed to afford 2-acyl-2-chlorocyclopropylcarboxylates.
Keywords
3,3-dihalo-1-azaallylic anion , activated olefin , MIRC reaction , (gamma)-amino acid , halogenated cyclopropane
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110304
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