Title of article
A new procedure for the preparation of 2-vinylindoles and their [4+2] cycloaddition reaction
Author/Authors
Yaseen Ali Mosa Mohamed، نويسنده , , Akira Matsuda and Fuyuhiko Inagaki، نويسنده , , Ryohei Takahashi، نويسنده , , Chisato Mukai، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2011
Pages
9
From page
5133
To page
5141
Abstract
A new approach for the synthesis of 2-vinylindole derivatives by 5-exo mode cyclization of 2-(3-silyloxymethylallenyl)anilines was developed. The starting allenylanilines were easily prepared by the Stille coupling of o-iodoaniline and allenylstannanes. The formed 2-vinylindole derivatives were transformed into several carbazole derivatives via the [4+2] cycloaddition reaction with suitable dienophiles.
Keywords
Allenes , 2-Vinylindoles , SN2’ reaction , Diels–Alder reaction
Journal title
Tetrahedron
Serial Year
2011
Journal title
Tetrahedron
Record number
1103414
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