• Title of article

    High-Pressure Enantioselective Allylation of Aldehydes Catalyzed by (Salen)Chromium(III) Complexes

  • Author/Authors

    Kwiatkowski، Piotr نويسنده , , Jurczak، Janusz نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2005
  • Pages
    -226
  • From page
    227
  • To page
    0
  • Abstract
    The enantioselective addition of allyltributyltin to simple aldehydes (2a-l), catalyzed by chiral (salen)Cr(III) complexes 1, has been studied. The reaction proceeds smoothly with low loading (1-2 mol%) of (salen)Cr(III)BF4 (1a) and allyltributyltin under high-pressure conditions (10 kbar) in good yield and ee values in the range of 35-79%.
  • Keywords
    Asymmetric Catalysis , Aldehydes , allylstannane , salen-chromium complexes , high-pressure technique , homoallylic alcohols
  • Journal title
    Synlett
  • Serial Year
    2005
  • Journal title
    Synlett
  • Record number

    110410

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=110410