Title of article
Study on the stereochemical control of dihydroxylation of vinyl epoxides and their derivatives
Author/Authors
Giuliana Righi، نويسنده , , Emanuela Mandic’، نويسنده , , Gaia Clara Mercedes Naponiello، نويسنده , , Paolo Bovicelli، نويسنده , , Ilaria Tirotta، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
9
From page
2984
To page
2992
Abstract
The results obtained from a study on the stereochemical control in the dihydroxylation of the double bond of vinyl epoxides and their derivatives (bromo derivatives, azido derivatives and vinyl aziridines) are presented herein. A significant diastereoselectivity was observed for the bromo derivatives, azido derivatives and N-protected vinyl aziridines, whereas vinyl epoxides and unprotected vinyl aziridines showed no diastereoselectivity. The results obtained are generally consistent with the Kishi model.
Keywords
Dihydroxylation , Vinyl epoxides , Vinyl aziridines , Azidoalcohols , Bromohydrins
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104355
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