Title of article
Mg(ClO4)2-catalyzed intramolecular allylic amination: application to the total synthesis of demethoxyfumitremorgin C
Author/Authors
Danfeng Jiang، نويسنده , , Zhengren Xu، نويسنده , , Yanxing Jia، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
8
From page
4225
To page
4232
Abstract
A Mg(ClO4)2-catalyzed intramolecular amination of allylic alcohols with carbamate or sulfonamide nucleophiles to form substituted piperidine and pyrrolidine derivatives has been developed. This method has been successfully applied to the total synthesis of demethoxyfumitremorgin C.
Keywords
Natural product , Magnesium , Amination , Total synthesis , Nitrogen heterocycles
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104508
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