Title of article
Toward the synthesis of γ-pyrone-containing natural products: diastereoselective aldol-type reaction of a γ-pyrone
Author/Authors
Takuma Takemura، نويسنده , , Jun-ichiro Hayakawa، نويسنده , , Emi Fukasawa، نويسنده , , Tetsuya Sengoku، نويسنده , , Hideo Kigoshi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2012
Pages
8
From page
6477
To page
6484
Abstract
The diastereoselective aldol-type reaction of a γ-pyrone via a sodium anion has been developed. This reaction is useful for synthesizing γ-pyrone-containing natural products. Also, we applied the Mukaiyama aldol-type reaction of silyl enol ether of γ-pyrone by using TiCl4. This Mukaiyama aldol-type reaction of γ-pyrone indicated higher anti-aldol selectivity than the aldol-type reaction of a γ-pyrone with NaHMDS.
Keywords
Mukaiyama aldol-type reaction of a ?-pyrone , anti-Aldol selectivity , Diastereoselective aldol-type reaction of a ?-pyrone
Journal title
Tetrahedron
Serial Year
2012
Journal title
Tetrahedron
Record number
1104774
Link To Document