• Title of article

    Baylis–Hillman acetates in carbocyclic synthesis: a convenient protocol for synthesis of densely substituted indenes

  • Author/Authors

    Deevi Basavaiah، نويسنده , , Bhavanam Sekhara Reddy، نويسنده , , Harathi Lingam، نويسنده ,

  • Issue Information
    هفته نامه با شماره پیاپی سال 2013
  • Pages
    10
  • From page
    1994
  • To page
    2003
  • Abstract
    A simple and facile strategy for synthesis of densely substituted indenes have been developed from Baylis–Hillman acetates in a two step protocol, that is, (1) via treatment with DABCO and then reaction with alkyl 3-oxobutanoates in the presence of K2CO3 (2) followed by the intramolecular Friedel–Crafts cyclization of the resulting keto-diesters using titanium tetrachloride.
  • Keywords
    Baylis–Hillman reaction , Friedel–Crafts reaction , Chemo selectivity , Keto-diesters , Indene derivatives
  • Journal title
    Tetrahedron
  • Serial Year
    2013
  • Journal title
    Tetrahedron
  • Record number

    1105517