Title of article
Radical conjugate addition of ambiphilic fluorinated free radicals
Author/Authors
Coralie De Schutter، نويسنده , , Emmanuel Pfund، نويسنده , , Thierry Lequeux، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
7
From page
5920
To page
5926
Abstract
The ambiphilic character of fluorinated radicals was noticed during their radical conjugate addition onto electron-deficient alkenes. Free radicals were trapped with enones when the reaction was conducted from iododifluoro-acetate and -phosphonate derivatives in the presence of Et3B. Competitive addition reaction onto electron-rich or -deficient alkenes was observed depending on the free radical initiator.
Keywords
Radical , Difluoromethyl , Phosphorus , Fluorine , Acetate
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1105984
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