Title of article
Copper-mediated cyanation of aryl boronic acids using benzyl cyanide
Author/Authors
Yan Luo، نويسنده , , Qiaodong Wen، نويسنده , , Zhiyuan Wu، نويسنده , , Jisong Jin، نويسنده , , Ping Lu، نويسنده , , Yanguang Wang، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2013
Pages
5
From page
8400
To page
8404
Abstract
An efficient copper-mediated synthesis of aryl nitriles from aryl boronic acids has been achieved using benzyl cyanide as a user-friendly cyanide source. Various aryl boronic acids underwent the reaction smoothly, affording the corresponding aryl nitriles in moderate to good yields. tert-Butyl hydroperoxide (TBHP) was found to be a critical agent facilitating the cyanation reaction.
Keywords
C–H oxidation , Boronic acid , Copper catalysis , Cyanation , Benzyl cyanide
Journal title
Tetrahedron
Serial Year
2013
Journal title
Tetrahedron
Record number
1106273
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