Title of article
Synthesis of 2,3-Dialkylindoles from 2-Alkenylphenylisocyanides and Imines by Silyltelluride- and Tin HydrideMediated Sequential Radical Reactions
Author/Authors
Yamago، Shigeru نويسنده , , Fukuyama، Tohru نويسنده , , Tokuyama، Hidetoshi نويسنده , , Kotani، Masashi نويسنده , , Satoh، Ayumu نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-1892
From page
1893
To page
0
Abstract
A new method for the synthesis of 2,3-dialkylindoles is described. The silyltelluride-mediated coupling reaction of imines and 2alkenylphenylisocyanides selectively occurred at the isocyanide moiety to give the corresponding imidoyltelluride. Tin hydridemediated intramolecular cyclization of the imidoyltelluride affords 2,3-dialkylindoles in good to excellent combined yields.
Keywords
indoles , Cyclization , Tellurium , radical reactions , isocyanides
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110662
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