Title of article
Kinetic resolution of primary amines via enantioselective N-acylation with acyl chlorides in the presence of supramolecular cyclodextrin nanocapsules
Author/Authors
Haruyasu Asahara، نويسنده , , Toshiyuki Kida، نويسنده , , Takuya Iwamoto، نويسنده , , Tomoaki Hinoue، نويسنده , , Mitsuru Akashi، نويسنده ,
Issue Information
هفته نامه با شماره پیاپی سال 2014
Pages
7
From page
197
To page
203
Abstract
The non-enzymatic kinetic resolution of primary amines via enantioselective N-acylation with acyl chlorides was accomplished for the first time by using the selective sequestration of one enantiomer within a supramolecular cyclodextrin (CD) nanocapsule in nonpolar solvents. In addition, the first example of a crystalline structure for an inclusion complex between an acyl chloride and a CD derivative is reported.
Keywords
Inclusion complex , Supramolecular nanocapsule , acyl chloride , Kinetic resolution , Cyclodextrin
Journal title
Tetrahedron
Serial Year
2014
Journal title
Tetrahedron
Record number
1106631
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