Title of article
Trimethylaluminum (TMA)-Catalyzed Reaction of Alkynyllithiums with Ethylene Oxide: Increased Yields and Purity of Homopropargylic Alcohols
Author/Authors
Brummond، Kay M. نويسنده , , McCabe، Jamie M. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
-2456
From page
2457
To page
0
Abstract
An efficient protocol was developed to obtain homopropargylic alcohols. Subjecting alkynyllithiums and ethylene oxide to 10-20 mol% of trimethylaluminum provided homopropargylic alcohols in good yields.
Keywords
alkynyllithiums , Nucleophilic additions , trimethylaluminum , homopropargylic alcohols , ethylene oxide
Journal title
Synlett
Serial Year
2005
Journal title
Synlett
Record number
110833
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