Title of article
Tribromoisocyanuric Acid: A New Reagent for Regioselective Cobromination of Alkenes
Author/Authors
Almeida، Leonardo S. de نويسنده , , Esteves، Pierre M. نويسنده , , Mattos، Marcio C. S. de نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
-1514
From page
1515
To page
0
Abstract
A simple one-step method for the preparation of tribromoisocyanuric acid in good yield (87%) has been developed. The reaction of tribromoisocyanuric acid with alkenes in presence of nucleophilic solvents (MeOH, i-PrOH, AcOH and a mixture of H2O-acetone, 1:5) led to the corresponding ?-bromoethers, ?-bromoacetates and bromohydrins, in high regioselectivity and good yields (73-98%).
Keywords
tribromoisocyanuric acid , oxone , cohalogenation , alkenes
Journal title
Synlett
Serial Year
2006
Journal title
Synlett
Record number
111182
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