• Title of article

    Stereoselective Syntheses of (E)-1-Boryl-3-(silyl)propenes via Ruthenium-­Catalyzed Cross-Metathesis and Cross-Coupling Reactions

  • Author/Authors

    Marciniec، Bogdan نويسنده , , Jankowska، Magdalena نويسنده , , Pietraszuk، Cezary نويسنده , , Zaidlewicz، Marek نويسنده ,

  • Pages
    -1694
  • From page
    1695
  • To page
    0
  • Abstract
    A general and mostly highly stereoselective method for effective synthesis of 1-boryl-3-(silyl)propenes via one-step ­catalytic processes, i.e. silylative coupling of vinylsilanes with allyl boronates, borylative coupling of vinyl boronates with allylsilanes catalysed by [RuHCl(CO)(PCy3)2] and cross-metathesis of respective derivatives in the presence of Grubbs catalysts, is described.
  • Keywords
    silylative coupling , cross-metathesis , Organic Synthesis , organosilicon compounds , Organoboron compounds
  • Journal title
    Astroparticle Physics
  • Record number

    111222

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=111222