Title of article
Synthesis, Structure, and the Unusual Magnetic Properties of an Amine-Templated Iron(II) Sulfate Possessing the Kagome Lattice
Author/Authors
Nagarajan، R. نويسنده , , Choudhury، Amitava نويسنده , , Rao، C. N. R. نويسنده , , Paul، Geo نويسنده , , Sampathkumaran، E. V. نويسنده , , Behera، J. N. نويسنده ,
Issue Information
ماهنامه با شماره پیاپی سال 2004
Pages
-1440
From page
1441
To page
0
Abstract
An amine-templated iron(II) sulfate of the composition [H3N(CH2)6NH3] [FeII1.5F3(SO4)]·0.5H2O, I, representing an example of a Kagome lattice with Fe in the +2 state, has been synthesized under solvothermal conditions. Having determined the structure by single -crystal X-ray diffraction, the oxidation state of iron was established by Mussbauer spectroscopy. The magnetic properties of the Fe(II) Kagome compound are rather unusual in that it undergoes ferrimagnetic ordering below 19 K and does not exhibit spin-glass freezing
Journal title
CHEMISTRY OF MATERIALS
Serial Year
2004
Journal title
CHEMISTRY OF MATERIALS
Record number
115206
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