Key properties promoting high activity and stability of supported PdSb/TiO2 catalysts in the acetoxylation of toluene to benzyl acetate Original Research Article

The influence of thermal pretreatment in air, helium and 10% H2/He on the catalytic performance of a supported 9% Pd, 12% Sb/TiO2 catalyst in the gas phase acetoxylation of toluene has been studied by integrated evaluation of catalytic tests and catalyst characterization using mainly XRD, TEM and XPS. A pretreatment temperature of 600 °C is beneficial for shortening the activation period, while the atmosphere during thermal pretreatment influences the long-term stability. Highest catalytic performance with a good long-term stability was reached with pretreatment in He, which creates Sb-containing Pd particles, on which a mixed Pd0/PdO surface is formed during time on stream. Sb stabilizes oxidized Pd species and leads to more stable catalysts in contrast to air-calcined samples. The catalyst pretreated in H2/He was completely inactive, due to the formation of a stable Pd8Sb3 alloy.