Title of article
Baeyer–Villiger oxidation of ketones catalysed by rhenium complexes bearing N- or oxo-ligands Original Research Article
Author/Authors
Elisabete C.B.A. Alegria، نويسنده , , Lu?sa M.D.R.S. Martins، نويسنده , , Marina V. Kirillova، نويسنده , , Armando J.L. Pombeiro، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
6
From page
27
To page
32
Abstract
Rhenium (I, III–V or VII) complexes bearing N-donor or oxo-ligands catalyse the Baeyer–Villiger oxidation of cyclic and linear ketones (e.g. 2-methylcyclohexanone, 2-methylcyclopentanone, cyclohexanone, cyclopentanone, cyclobutanone and 3,3-dimethyl-2-butanone) into the corresponding lactones or esters, in the presence of aqueous H2O2 (30%). The effects of various reaction parameters are studied allowing to achieve yields up to 54%.
Keywords
Rhenium complexes , Hydrogen peroxide , Ketones , Homogeneous catalysis , Lactones , C-scorpionates , Pyrazole , Baeyer–Villiger oxidation
Journal title
Applied Catalysis A:General
Serial Year
2012
Journal title
Applied Catalysis A:General
Record number
1157051
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