Title of article
A thermal decomposition study on cobalt(II) complexes of 1,2-di(imino-4′-antipyrinyl)ethane
Author/Authors
N.T Madhu، نويسنده , , P.K Radhakrishnan، نويسنده , , Matthias Grunert، نويسنده , , Peter Weinberger، نويسنده , , Wolfgang Linert، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2003
Pages
8
From page
29
To page
36
Abstract
The phenomenological, kinetic and mechanistic aspects of thermal decomposition of perchlorate, nitrate, chloride, bromide and iodide complexes of cobalt(II) with the Schiff base 1,2-di(imino-4′-antipyrinyl)ethane (GA) have been studied by TG and DTG analyses. The kinetic parameters like the activation energy, pre-exponential factor and entropy of activation were calculated. The decomposition reactions follow “random nucleation with one nucleus on each particle—Mampel model”.
Keywords
Decomposition , kinetics , Coats-Redfern , Cobalt(II) complexes
Journal title
Thermochimica Acta
Serial Year
2003
Journal title
Thermochimica Acta
Record number
1195973
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