Thermogravimetric characterization of sulfonated poly(styrene-isobutylene-styrene) block copolymers: effects of processing conditions

In this study, sulfonated poly(styrene-isobutylene-styrene) (S-SIBS) block copolymers were characterized by thermogravimetry as a function of four different processing conditions: sulfonation level, annealing temperature, film formation, and casting solvent. Sulfonated samples showed an increase in degradation temperature from 432 to 450 °C compared to the unsulfonated polymer, regardless of sulfonation level or other processing condition. Sulfonated samples also showed an additional minor loss of mass at approximately 290 °C, which was not observed in the unsulfonated polymer. At this temperature, desulfonation or a cleavage reaction of the aromatic carbon–sulfur bond occurs. In addition, annealing the sulfonated block copolymer at a higher temperature (180 °C) for an extended period of time also results in a partial desulfonation. These results were confirmed by a reduction in water sorption and in intensity of the infrared bands associated with sulfonic acid. There was no change in thermal stability in S-SIBS block copolymers as a function of film formation (solvent cast versus heat pressed) and casting solvent (six different solvents).