Title of article
Calorimeteric and NMR binding studies of hydrogen-bonding receptors for carboxylates
Author/Authors
Mohammad H. Al-Sayah، نويسنده , , Neil R. Branda، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2010
Pages
5
From page
28
To page
32
Abstract
Two receptors (1 and 2) were designed and prepared to bind carboxylate anions through donor–donor hydrogen-bonding motifs provided by thiourea (1) and squaramide (2) groups. The binding efficacy of each receptor was studied using NMR and isothermal calorimetric titrations in DMSO and CH3CN/CHCl3 solvent systems. Binding constants and changes in enthalpy and entropy of the binding process were calculated and evaluated.
Keywords
Anion binding , ITC titrations , Squaramide , NMR titrations , Synthetic receptors
Journal title
Thermochimica Acta
Serial Year
2010
Journal title
Thermochimica Acta
Record number
1199444
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