Nonisothermal crystallization kinetics of ethylene terephthalate–ethylene oxide segmented copolymers with two crystallizing segments

The nonisothermal crystallization behavior of ethylene terephthalate–ethylene oxide segmented copolymers has been studied by means of differential scanning calorimetry (DSC). The kinetics of ET–EO segmented copolymer under nonisothermal crystallization conditions has been analyzed by the Ozawa equation. During the crystallization of the high-Tm segments (PET), the low-Tm segments (PEO) act as a noncrystalline diluent, the crystallization behavior of PET obeys the Ozawa theory. When the PEO segments begin to crystallize, the PET phase is always partially solidified and the presence of the spherulitic microstructure of PET profoundly influences the crystallization behavior, which results in that the overall crystallization process does not obey the Ozawa equation.