Title of article
1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) as ligand for atom transfer radical polymerization (ATRP)
Author/Authors
David Fournier، نويسنده , , Marie-Laure Romagné، نويسنده , , Sagrario Pascual، نويسنده , , Véronique Montembault، نويسنده , , Laurent Fontaine، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
6
From page
1576
To page
1581
Abstract
1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) has been used as a bidentate ligand of copper (I) bromide for the ATRP of (meth)acrylates and styrene. With methyl methacrylate, the polymerization reached high conversions producing polymers with a good control of Mn and low polydispersity indexes (PDI = 1.19). Higher PDI were obtained with polystyrenes and poly(methyl acrylate)s. These results have been correlated to the redox properties of the catalytic complex.
Keywords
Electrochemistry , Nitrogen bidentate ligand , Atom transfer radical polymerization (ATRP) , DBU , Copper complex
Journal title
European Polymer Journal(EPJ)
Serial Year
2005
Journal title
European Polymer Journal(EPJ)
Record number
1212740
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