Effects of seawater on AAR expansion of concrete

Recently, AAR was identified in submerged piles of some bridges in tidal waters. Microstructural examination detected chloroaluminate salts in some cracks. To clarify whether seawater had influenced the deterioration an experimental program was planned to examine the effects of sodium chloride on AAR under various curing conditions. Concrete prisms containing either of highly-reactive, slowly-reactive or nonreactive aggregate, and either low or high alkali contents, were stored in saltwater (representing seawater) or at 100% RH, at temperatures of 38, 60 and 80 °C, for expansion measurement over 600 days, after which the temperature for those stored in saltwater was lowered to 23 °C, to check its effect on further expansion, which could be attributed to precipitation of ettringite and/or Ca-chloroaluminate. The results indicate that the type of aggregate and concrete alkali content had the greatest effect on AAR expansion. Exposure to saltwater did not have any significant effect on the AAR expansion.