Title of article
H2O2/NaHCO3-mediated enantioselective epoxidation of olefins in NTf2-based ionic liquids and under ultrasound
Author/Authors
Gregory Chatel، نويسنده , , Catherine Goux-Henry، نويسنده , , Anaïs Mirabaud، نويسنده , , Thomas Rossi، نويسنده , , Nathalie Kardos، نويسنده , , Bruno Andrioletti، نويسنده , , Micheline Draye، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
6
From page
127
To page
132
Abstract
The bicarbonate-activated peroxide (BAP) system has been shown to constitute an excellent and versatile combination for the epoxidation of olefins. Herein, we demonstrate that the benign H2O2/NaHCO3 oxidative combination can be used for the enantioselective epoxidation of olefins using a chiral manganese porphyrin as a catalyst. This unprecedented result was made possible by the use of an ionic liquid with ultrasound, which leads to the activation of Mn-porphyrin catalysis.
Keywords
In situ XRD , Platinum , Hydrogen production , Cerium oxide , Ruthenium , Water–gas shift , Operando XANES , DRIFTS–WGSR , Alloy , formate
Journal title
Journal of Catalysis
Serial Year
2012
Journal title
Journal of Catalysis
Record number
1223579
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