Title of article
Microwave-assisted Cr(salen)-catalysed asymmetric ring opening of epoxides
Author/Authors
Bart M.L. Dioos، نويسنده , , Pierre A. Jacobs، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
3
From page
428
To page
430
Abstract
The effect of microwaves on the kinetics and the selectivity of the Cr(salen)-catalysed asymmetric ring opening of epoxides was investigated. It was found that the reaction rate of the Cr(salen)-catalysed kinetic resolution of terminal epoxides and the asymmetric ring opening (ARO) of meso-epoxides could be increased by three orders of magnitude without impairing the selectivity.
Keywords
Catalytically active titanium species , Silylation , hydroxylation , epoxidation , 29Si MAS NMR spectroscopy , Mesoporous titanosilicate
Journal title
Journal of Catalysis
Serial Year
2005
Journal title
Journal of Catalysis
Record number
1224138
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