Title of article
QUANTUM-CHEMICAL MODELING OF THE MECHANISM OF AUTOCATALYTIC DEHYDROCHLORINATION OF PVC
Author/Authors
Yanborisov، V.M. نويسنده , , Borisevich، S.S. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
7
From page
352
To page
358
Abstract
The thermodynamic parameters were calculated for the dehydrochlorination of low-molecular compounds simulating normal vinyl chloride chains and _-chloroallyl and polyenyl chloride groups. It was established that HCl does not affect the dehydrochlorination of vinyl chloride units with normal structure but catalyzes the elimination from sections of the macromolecules that contain C=C double bonds.
Keywords
polyvinyl chloride , autocatalytic dehydrochlorination , quantum-chemical calculations
Journal title
Theoretical and Experimental Chemistry
Serial Year
2005
Journal title
Theoretical and Experimental Chemistry
Record number
122473
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