• Title of article

    Polemic against conclusions drawn in “Shape-selective diisopropylation of naphthalene in H-Mordenite: Myth or reality?” (J. Catal., 270 (2010) 60–66)

  • Author/Authors

    Robert Brzozowski، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2011
  • Pages
    5
  • From page
    137
  • To page
    141
  • Abstract
    In the article mentioned in the title, the authors challenged the hypothesis on shape-selective formation of 2,6-diisopropylnaphthalene (2,6-DIPN) in isopropylation of naphthalene over H-MOR catalysts. They claimed it was a myth, and there was no need to explain the high 2,6-DIPN selectivity with shape selectivity because it was in the range predicted by kinetics and thermodynamics. They also suggested that improper analysis of DIPN products could be a reason of the high 2,6-DIPN selectivity observed in the literature. However, in the current article I proved that some experimental results cannot be explained by kinetics, thermodynamics and analytical errors; therefore, shape-selective diisopropylation of naphthalene over H-mordenite is still the reality.
  • Keywords
    PT , Aberration-corrected TEM , NO oxidation catalysts , Pt–Pd alloys
  • Journal title
    Journal of Catalysis
  • Serial Year
    2011
  • Journal title
    Journal of Catalysis
  • Record number

    1226248