Finite deformation of a polymer: experiments and modeling

The response of a polymer (polytetrafluoroethylene) to quasi-static and dynamic loading is determined and modeled. The polytetrafluoroethylene is extremely ductile and highly nonlinear in elastic as well as plastic behaviors including elastic unloading. Constitutive model developed earlier by Khan, Huang and Liang (KHL) is extended to include the responses of polymeric materials. The strain rate hardening, creep, and relaxation behaviors of polytetrafluoroethylene were determined through extensive experimental study. Based on the observation that both viscoelastic and viscoplastic deformation of polytetrafluoroethylene are time dependent and nonlinear, a phenomenalogical viscoelasto–plastic constitutive model is presented by a series connection of a viscoelastic deformation module (represented by three elements standard solid spring dashpot model), and a viscoplastic deformation module represented by KHL model. The KHL module is affected only when the stress exceeds the initial yield stress. The comparison between the predictions from the extended model and experimental data for uniaxial static and dynamic compression, creep and relaxation demonstrate that the proposed constitutive model is able to represent the observed time dependent mechanical behavior of polytetrafluoroethylene polytetrafluoroethylene qualitatively and quantitatively.