Characterizing hyporheic transport processes — Interpretation of electrical geophysical data in coupled stream–hyporheic zone systems during solute tracer studies

Quantifying hyporheic solute dynamics has been limited by our ability to assess the magnitude and extent of stream interactions with multiple domains: mobile subsurface storage (MSS, e.g., freely flowing pore water) and immobile subsurface storage (ISS, e.g., poorly connected pore water). Stream-tracer experiments coupled with solute transport modeling are frequently used to characterize lumped MSS and ISS dynamics, but are limited by the ability to sample only “mobile” water and by window of detection issues. Here, we couple simulations of near-surface electrical resistivity (ER) methods with conservative solute transport to directly compare solute transport with ER interpretations, and to determine the ability of ER to predict spatial and temporal trends of solute distribution and transport in stream–hyporheic systems. Results show that temporal moments from both ER and solute transport data are well correlated for locations where advection is not the dominant solute transport process. Mean arrival time and variance are especially well-predicted by ER interpretation, providing the potential to estimate rate-limited mass transport (i.e. diffusive) parameters from these data in a distributed domain, substantially increasing our knowledge of the fate and transport of subsurface solutes.