Title of article
Molecular structure design based on Lewis acid–base interaction in the preparation of bimetallic alkoxides derived from two electronegative elements. The synthesis and X-ray single crystal study of Mo2Ta4O8(OMe)16 and Mo4Ta2O8(OiPr)14
Author/Authors
Anders Johansson، نويسنده , , Vadim G. Kessler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
3
From page
5
To page
7
Abstract
Complex formation between molybdenum and tantalum alkoxides has been achieved via activation of the homometallic species, both being Lewis acids, by either partial hydrolysis or partial thermolysis in hydrocarbon media. The crystal structures of the products formed, Mo2Ta4O8(OMe)16 (I) and Mo4Ta2O8(OiPr)14 (II) respectively, are described.
Keywords
crystal structures , Molybdenum complexes , Tantalum complexes , Alkoxide complexes
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314790
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