• Title of article

    Reactions of platinum(II)–nitrile complexes with amines. Synthesis, characterization and X-ray structure of the platinum(II)–amidine complex trans-[PtCl2{Z-N(H)C(NHMe)Me}2]

  • Author/Authors

    Roberta Bertani، نويسنده , , Demetrio Catanese، نويسنده , , Rino A Michelin، نويسنده , , Mirto Mozzon، نويسنده , , Giuliano Bandoli، نويسنده , , Alessandro Dolmella، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2000
  • Pages
    3
  • From page
    16
  • To page
    18
  • Abstract
    The reaction of trans-[PtCl2(NCMe)2] with a 5-fold excess of MeNH2 in CH2Cl2 at −10°C affords in high yield the bis-amidine complex trans-[PtCl2{Z-N(H)C(NHMe)Me}2] (1), where both the amidine ligands assume the Z configuration corresponding to the trans addition of the amine along the CN triple bond. Compound 1 has been fully characterized by spectroscopic techniques and also by X-ray diffraction analysis.
  • Keywords
    Platinum complexes , Nitrile complexes , Amidine complexes , crystal structures
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2000
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1314794

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1314794