Title of article
Hydrothermal synthesis of [Ba3Cl2][Sn3O4(OH)8], a compound with alternating ionic and covalent layers
Author/Authors
Mingmei Wu، نويسنده , , Xiulin Li، نويسنده , , Guoping Shen، نويسنده , , Alvin Siu، نويسنده , , Samuel M.-F Lo، نويسنده , , Herman H.-Y Sung، نويسنده , , Ian D. Williams، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
3
From page
99
To page
101
Abstract
[Ba3Cl2][Sn3O4(OH)8] (1), is formed through hydrothermal synthesis in the BaCl2/SnCl4 system. 1 is orthorhombic, Pnma, a=7.836(2), b=18.350(4), c=10.258(2) Å, V=1475 Å3 and composed of alternating layers of covalent stannate and ionic barium chloride components. The ‘covalent’ layers consist of hydroxy stannate trimers [Sn3O4(OH)8], connected through μ3-O to other units forming puckered 2-D sheets. These sheets are then intercalated by the barium and chloride ions, which have a complex set of ionic contacts.
Keywords
Intercalation , Hydrothermal synthesis , Tin oxides , Layer compounds
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314818
Link To Document