Title of article
A novel functionalized P,C,P pincer ligand complex
Author/Authors
Jost C Grimm، نويسنده , , Christiane Nachtigal، نويسنده , , H.-G Mack، نويسنده , , William C Kaska، نويسنده , , Hermann A. Mayer، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
4
From page
511
To page
514
Abstract
Reaction of 3,5-di(bromomethyl)nitrobenzene with di-t-butylphosphine and subsequent treatment with sodium acetate gives the novel functionalized P,C,P pincer ligand 2. Heating an isopropanol/water solution of 2 with iridium(III)chloride results in the iridium hydrochloride complex 3. This complex was characterized by X-ray structure analysis in the solid state, NMR spectroscopy in solution, and density functional calculations in the gas phase.
Keywords
Pincer ligands , X-ray structure , iridium complexes , Quantum chemical calculations
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314926
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