Title of article
A molecular propeller with three quadruply-bonded blades
Author/Authors
F. Albert Cotton، نويسنده , , Lee M. Daniels، نويسنده , , Chun Lin، نويسنده , , Carlos A. Murillo، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
4
From page
130
To page
133
Abstract
Reaction of the trinegative tricarboxylate anion 1,3,5-tricarboxylatobenzene (the anion of trimesic acid) and Mo2(DAniF)3Cl2 (DAniF=N,N′-di-p-anisylformamidinate) under reducing conditions produces the propeller-shaped hexanuclear complex [Mo2(DAniF)3]3(1,3,5-C6H3(CO2)3). Its structure has been established by X-ray crystallography; 1H NMR is also consistent with the presence of highly symmetrical species in solution. The three quadruply-bonded Mo–Mo distances are 2.082(4), 2.087(3), and 2.090(4) Å. This neutral complex is electrochemically active.
Keywords
Trimesic acid. , Dimolybdenum quadruple bonds , Hexanuclear complex , Supramolecular chemistry , Electrochemistry
Journal title
Inorganic Chemistry Communications
Serial Year
2001
Journal title
Inorganic Chemistry Communications
Record number
1315012
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