• Title of article

    New polymeric structure of rhenium octahedral chalcocyanide complex: Ln3+-derived network with one-dimensional channels

  • Author/Authors

    Sofia B Artemkina، نويسنده , , Nikolai G. Naumov ، نويسنده , , Alexander V Virovets، نويسنده , , Sergey A Gromilov، نويسنده , , Dieter Fenske، نويسنده , , Vladimir E Fedorov، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    4
  • From page
    423
  • To page
    426
  • Abstract
    A novel cyanobridged coordination polymeric complex with octahedral rhenium cyanocluster anion [Re6(μ3−Se)8(CN)6]4− and Nd3+ cation has been synthesised and structurally characterised. Its solid-state structure contains a channel-type polymeric network built from cluster anions and Nd3+ through ReCNNdNCRe interactions. For compound (H3O){Nd(DMF)3(H2O)3}[Re6Se8(CN)6], space group R3c, unit cell parameters are: a=32.514(5); c=25.255(5) Å, V=23122(7) Å3, Rf=0.0762. A pair of isomorphic complexes has been obtained with Ln=Pr3+,Ho3+.
  • Keywords
    Rhenium , Octahedral cluster , Lanthanide , Polymeric structure , Cyano-bridged complexes
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2001
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1315105

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1315105