Title of article
Perrhenate ligand as an analog of the methoxide group in alkoxide complexes. Synthesis and X-ray single crystal study of Ta2(OMe)8(ReO4)2
Author/Authors
Gulaim A. Seisenbaeva، نويسنده , , Vadim G. Kessler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
3
From page
534
To page
536
Abstract
The interaction of Ta2(OMe)10 with Re2O7 in toluene in 1:2 ratio provided an approach to a new bimetallic complex, Ta2(OMe)8(ReO4)2(I), which in its solid state structure and solution behavior displayed a close analogy to the homometallic M2(OMe)10, M=Nb, Ta, and to M2O2(OMe)8, M=Mo, W, complexes.
Keywords
Metal alkoxides , Methoxide , X-ray structure , Rhenium complexes , Solution dynamics
Journal title
Inorganic Chemistry Communications
Serial Year
2001
Journal title
Inorganic Chemistry Communications
Record number
1315159
Link To Document