Title of article
Carboranylamidinates of di- and trivalent iron
Author/Authors
Philipp Hillebrand، نويسنده , , Cristian G. Hrib، نويسنده , , Nicole Harmgarth، نويسنده , , Peter G. Jones ، نويسنده , , Volker Lorenz، نويسنده , , Marcel Kühling، نويسنده , , Frank T. Edelmann، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
3
From page
127
To page
129
Abstract
For the first time, carboranylamidinates of a transition metal in two different oxidation states have been prepared. The iron carboranylamidinates [o-C2B10H10C(NHiPr)(= NiPr)-κ2C,N]2FeIIICl (3) and [o-C2B10H10C(NHiPr)(= NiPr)-κ2C,N]2FeII (4) were simultaneously formed in low yields upon treatment of anhydrous FeCl3 with 2 equiv. of [o-C2B10H10C(NHiPr)(= NiPr)-κ2C,N]Li(DME) (2) in THF solution. Both products were structurally characterized by single-crystal X-ray diffraction.
Keywords
Iron , Carboranylamidinates , Amidinates , X-ray structure , Carboranes
Journal title
Inorganic Chemistry Communications
Serial Year
2014
Journal title
Inorganic Chemistry Communications
Record number
1315478
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