Title of article
[Ph4P][CrO3(OH)] – a wonder molecule: its behaviour as a bifunctional autocatalyst in water-splitting for the perpetual generation of dihydrogen and a catalyst mimicking catalase function
Author/Authors
Ratna Bandyopadhyay، نويسنده , , Swarup K. Maiti، نويسنده , , Ramgopal Bhattacharyya، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
5
From page
259
To page
263
Abstract
An oxygen-rich chromium (VI) complex, Ph4P[CrO3(OH)], reduces water present in non-aqueous media, viz, acetonitrile or dichloromethane to dihydrogen fuel autocatalytically, while oxidising functionalized organic substrates. The same catalyst also shows a catalase like activity on H2O2 also in non-aqueous media.
Keywords
Autocatalysis , Catalase activity , Oxygen-rich chromium (VI) complex , Water-splitting to dihydrogen
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315539
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