Title of article
A co-ligand firstly introduced to 9-fluorenone-2,7-dicarboxylate-based MOF: synthesis, structure and photoluminescent property
Author/Authors
Yi-Qiang Mu، نويسنده , , Min-Le Han، نويسنده , , Bing-Hai Wang، نويسنده , , Wei Xia، نويسنده , , Wen-Wen Dong، نويسنده , , Dong-Sheng Li، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2014
Pages
4
From page
259
To page
262
Abstract
Through hydrothermal reactions, 4,4′-bipyridine (bpy) co-ligands firstly was introduce to CdII–H2FDC system (H2FDC = 9-fluorenone-2,7-dicarboxylic acid), generating a new coordination polymer {[Cd2(FDC)2(bpy)]∙H2O}n (1). Compound 1 has a pillar-layer 2-fold interpenetrating pcu network, based on the square-grid tetranuclear [Cd4(COO)8] units. Interestingly, 1 shows a blue-shifted photoemission, as well as enhanced fluorescence lifetime compared with the pure H2FDC ligand.
Keywords
CdII-MOFs , 7-dicarboxylate , crystal structure , Luminescence property , 9-Fluorenone-2
Journal title
Inorganic Chemistry Communications
Serial Year
2014
Journal title
Inorganic Chemistry Communications
Record number
1315565
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